Blar i SINTEF Open på forfatter "Holmsen, Marte Sofie"

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    • A highly asymmetric gold(III) η3‐allyl complex 

      Holmsen, Marte Sofie; Nova, Ainara; Øien-Ødegaard, Sigurd; Heyn, Richard H.; Tilset, Mats (Journal article; Peer reviewed, 2019)
      A highly asymmetric AuIII η3‐allyl complex has been generated by treating Au(η1‐allyl)Br(tpy) (tpy=2‐(p‐tolyl)pyridine) with AgNTf2. The resulting η3‐allyl complex has been characterized by NMR spectroscopy and X‐ray ...

    • Markovnikov at Gold: Nucleophilic Addition to Alkenes at Au(III) 

      Holmsen, Marte Sofie; Ihlefeldt, Franziska; Øien-Ødegaard, Sigurd; Langseth, Eirin; Wencke, Yannick; Heyn, Richard H.; Tilset, Mats (Peer reviewed; Journal article, 2018)
      The reactivity of Au(OAcF)2(tpy) (1, OAcF = OCOCF3; tpy = 2-(p-tolyl)pyridine) toward a wide variety of different alkenes with various substitution patterns and different oxygen-based nucleophiles has been investigated. ...

    • trans-Mutation at Gold(III): A mechanistic study of a catalytic acetylene functionalization via a double insertion pathway 

      Holmsen, Marte Sofie; Nova, Ainara; Balcells, David; Langseth, Eirin; Øien-Ødegaard, Sigurd; Heyn, Richard H.; Tilset, Mats; Laurenczy, Gábor (Peer reviewed; Journal article, 2017)
      The Au(III) complex Au(tpy)(OAcF)2 (OAcF = OCOCF3; tpy = 2-(p-tolyl)pyridine) catalyzes the anti addition of trifluoroacetic acid (HOAcF) to acetylene to furnish vinyl trifluoroacetate. The Au(III) vinyl complex ...